Methylammonium antimony sulfide.

نویسندگان

  • Rachel J E Lees
  • Anthony V Powell
  • Ann M Chippindale
چکیده

Bis(methylammonium) octaantimony(III) dodecasulfide persulfide, (CH3NH3)2[Sb8S12(S2)], contains pairs of [Sb4S7]2- chains joined through an unusual persulfide bond to create infinite double [Sb8S14]2- chains. The double chains are interlocked by longer Sb...S interactions to form sheets approximately parallel to the (101) crystallographic plane. Methylammonium cations, formed by decomposition of 2-methylpropane-1,2-diamine during the synthesis, are located in large (Sb8S10) hetero-ring apertures created within the double chains.

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عنوان ژورنال:
  • Acta crystallographica. Section C, Crystal structure communications

دوره 61 Pt 12  شماره 

صفحات  -

تاریخ انتشار 2005